Bruce Manning, Ph.D.
Associate Professor
Analytical and Environmental Chemistry
Office: Thornton Hall 811-B
Phone: 415-338-1292
Fax: 415-338-2384
E-mail: bmanning@sfsu.edu
Education
B.S., cum laude, Environmental Science, University of
Massachusetts, 1985
Ph.D. Environmental Chemistry, University of
California, Davis, 1993
Research Interests
Surface Analysis: Determination of the coprecipitation
and adsorption reaction mechanisms of metals and oxyanions
on synthetic and natural surfaces such as metal oxides and clay minerals; use
of extended X-ray absorption fine structure spectroscopy (EXAFS) and X-ray
absorption near-edge structure (XANES) spectroscopy for elucidation of the
structure of metal ion surface complexes; surface imaging by SEM with
elemental analysis by EDAX; heterogeneous redox
reactions of As, Cr, and Se at mineral surfaces; application of X-ray
photoelectron spectroscopy (XPS) to corrosion and adsorption reactions in
environmental remdiation.
Facilities for X-ray Spectroscopy:
Stanford Synchroton Radiation
Laboratory (SSRL)
Link:
http://www-ssrl.slac.stanford.edu/
Link:
http://www.aps.anl.gov/
The Frederick Seitz Materials Research Laboratory,
Link: http://www.mrl.uiuc.edu/
Mineralogy: Crystallographic determination by X-ray
diffraction, surface area analysis using BET N2 and EGME adsorption techniques,
particle surface charge measurements by electrophoretic
mobility. Mineralogical analysis of soil
and soil physical property characterization.
Our group was recently awarded funds from NSF for a powder X-ray diffractometer (Bruker D8
ADVANCE) with Goebell mirror primary beam optics and
Sol-X solid state detector system.
Remediation: Development and characterization of sorbent solids such as synthetic metal oxides and metal
oxide-coated substrates, nanoscale zero-valent iron, supported zero-valent
iron. Applications include remediation of waste waters and drinking water
containing metal cation contaminants (e.g. Pb(II), Cd(II), Zn(II)) and
anions (As(V), Cr(VI), Se(VI)).
Inorganic Chemical Analysis: Determination of metals and
trace elements by atomic absorption spectrometry (AAS), inductively coupled
plasma optical emission spectrometry (ICP-OES), ICP-MS spectrometry,
graphite-furnace electrothermal AAS, and UV-VIS
spectrometry. Separation and detection of redox
sensitive elements (As(III)/As(V), Se(IV)/Se(VI), and Cr(III)/Cr(VI)) by
hyphenated techniques such as ion chromatography coupled with atomic absorption
spectrometry (AAS), inductively coupled plasma (ICP) and ICP-MS
spectrometry. Determination of organic derivatives of As and Se in
biological systems.
Chemical
Modeling:
Equilibrium chemical modeling of redox speciation,
precipitation, and adsorption reaction constants in environmental systems using
PHREEQC, GEOCHEM and MINTEQ; Surface complexation
modeling of mineral surfaces with FITEQL; Simulation of contaminant transport
in soil and porous media using UNSATCHEM reactive solute transport model.
Honors
and Awards
2001-2005 Research Corporation Cottrell College Science Award Fellow
2004 SFSU
President's Assigned Time Award Recipient (Spring 2004 semester)
2000-2001 DuPont Corporation Aid to Education
Research Fellow
1997-1999 USDA-National Research Initiative (NRI) Competitive Grants
Postdoctoral Fellow
1989-1992 National Institute of Environmental Health Sciences (NIEHS)
Graduate Fellow Department of Environmental Toxicology, U.C. Davis
Research Grants
2005 ACS-PRF
Type B Program. ($50K). Title:
Spectroscopic investigation of supported nanoscale
zerovalent iron for arsenic(V) and chromium(VI)
remediation (in preparation).
2005 California
Bay Delta Authority (CALFED) ($300K).
Title: Release and Transformation
of Peat Soil Derived Dissolved Organic Carbon:
A Natural Precursor for Chlorinated Disinfection By-products. (in preparation).
2005 Morris
Animal Foundation (
2005 Research
Corporation,
2004 National
Science Foundation-Major Research Instrumentation (MRI) Program ($197K). Title:
Acquisition of an X-ray Diffractometer for
Environmental and Materials Chemistry Research.
2004 Argonne
National Lab APS beamtime proposal. Application of synchrotron radiation
techniques to nanoscale zerovalent
iron remediation materials for arsenic(V) and chromium(VI).
2003 San
Francisco State University Presidential Award for Professional Development of
Probationary Faculty Leave with Pay Application (0.5 AY pay). Title:
Development of Advanced Analytical Techniques to Study Soil and Groundwater
Remediation Materials.
2002
2002
2001 Research
Corporation,
2000
2000 Faculty
Minigrant.
2000
1999
1999 DuPont Aid to Education Grant ($10K). Title:
Advanced Techniques for Studying the Chemistry and Remediation of
Arsenic.
1997 National
Research Initiative (NRI) competitive Grants program postdoctoral award
($82K). Title: Transformation and Transport
of Arsenic(III) and Arsenic(V) in Soil Columns.
1990 National
Institute of Environmental Health Sciences (NIEHS) Graduate Training Grant
Fellowship ($15K/yr) for environmental chemistry and health-related disciplines
(Department of Environmental Toxicology, U.C. Davis).
Publications
Manning,
B.A.; Kiser, J.; Kwon, H.C.; Gewirth, A. 2005.
Reduction of chromium(VI) and coprecipitation
of Cr(III) oxide/hydroxide on nano-scale iron
particle surfaces. Environ. Sci. Technol. (in
preparation).
Kanel,
S.R.; Manning, B.A.; Choi, H. 2005.
Transport of surfactant stabilized iron nanoparticles
in porous media and application to
arsenic remediation. Environ. Sci. Technol. (submitted).
Manning,
B.A. 2005. (Invited Article). Arsenic speciation in As(III)- and
As(V)-treated soil using XANES spectroscopy.
Microchimica Acta. Special issue devoted to: "Novel analytical methodologies for the
determination of arsenic species in solids, liquids and gases." (in press).
Kanel,
S.R.; Manning, B.A.; Charlet, L; Choi,
H. 2005.
Removal of arsenic(III) from groundwater by nano-scale
zero-valent iron.
Environ. Sci. Technol.
39, 1291-1298.
Bostick, B.; Fendorf, S.E.; Manning,
B.A. 2003. Arsenite adsorption
on galena (PbS) and sphalerite
(ZnS). Geochim. Cosmochim. Acta. 67, pp. 895-907.
Nguyen,
Q.T.; Manning, B.A. 2003. Spectroscopic and modeling study of lead
adsorption
and precipitation reactions on a mineral soil. In Biogeochemistry of
Environmentally Important Trace Elements. Cai, Y.; Braids,
O.C. Eds; ACS Book Series 835; American
Chemical Society, Washington, DC, 2002; pp.388-403.
Manning,
B.A.; Fendorf, S.E.; Suarez, D.L. 2003. Arsenic(III) complexation
and oxidation reactions on soil. In Biogeochemistry of Environmentally
Important Trace Elements. Cai, Y.; Braids, O.C. Eds; ACS
Book Series 835; American Chemical Society, Washington, DC, 2002;
pp.57-69.
Manning,
B.A.; Fendorf S.E.; Suarez, D.L. 2002. Arsenic(III)
oxidation and arsenic(V) adsorption reactions on synthetic birnessite.
Environ. Sci. Technol.
36, 976-981.
Manning,
B.A.; Hunt, M.; Amrhein, C.; Yarmoff,
J.A. 2002. Arsenic(III) and arsenic(V)
reactions with zerovalent iron corrosion
products. Environ. Sci. Technol. 36, 5455-5461.
Manning,
B.A.; D.L. Suarez. 2000. Modeling arsenic(III)
adsorption and heterogeneous oxidation kinetics in soils. Soil Sci. Soc.
Am. J. 64, 128-137.
Manning,
B.A.; Fendorf, S.E.; Suarez, D.L. 1999. Arsenate Surface Complexes in Soil and Model
Compounds. American Chemical
Society. Proceedings of Division of
Environmental Chemistry, Extended Abstracts, 1999, 39, 288-290.
Manning,
B.A. 1998. Selenium immobilization by in situ precipitation of ferric oxyhydroxide. In R.A.Meyers
(ed.) The Encyclopedia of Environmental Analysis and Remediation. John Wiley & Sons,
Manning,
B.A.; Fendorf, S.E.; Goldberg, S. 1998. Surface
structures and stability of arsenic(III) on goethite: Spectroscopic evidence
for inner‑sphere complexes. Environ. Sci. Technol, 32, 2383-2388.
Manning,
B.A.; Martens, D.A. 1997. Speciation of arsenic(III) and arsenic(V) in
sediment extracts by high performance liquid chromatography-hydride generation
atomic absorption spectrophotometry. Environ. Sci. Technol. 31: 171-177.
Manning,
B.A.; Goldberg, S. 1997. Adsorption and
stability of arsenic(III) at the clay mineral-water interface. Environ. Sci. Technol, 31, 2005-2011.
Manning,
B.A.; Goldberg, S. 1997. Arsenic(III) and arsenic(V) adsorption on
three
Manning,
B.A.; Goldberg, S. 1996. Modeling
competitive adsorption of arsenate with phosphate and molybdate
on oxide minerals. Soil Sci. Soc. Am. J. 60:
121-131.
Manning,
B.A.; Goldberg, S. 1996. Modeling
arsenate competitive adsorption on kaolinite, montmorillonite, and illite. Clays
& Clay Miner. 44: 609-623.
Manning,
B.A.; Burau, R.G. 1995. Selenium immobilization in evaporation pond
sediment by in situ precipitation of ferric oxyhydroxide. Environ. Sci. Technol. 29:2639-2646.
Conference
Proceedings and Abstracts
Chow, A.T,
Dahlgren, R.A., Manning, B.A., Mazet, J.A.
2005. The Propensity in
Disinfection Byproduct Formation from Various Dissolved Organic Carbon Sources.
IRACDA Meeting,
Manning,
B.A., Kiser, J., Kanel, S.R., Choi,
H. 2004.
Removal of Arsenic(III) from Groundwater with Nano
Scale Zero-Valent Iron. American Geophysical
Manning, B.A., Jakovleski, V. Peterson,
T.M. 2003. Arsenic Speciation and
Heterogeneous Redox Reactions in Soil Systems. Soil Sci. Soc.
Annual Mtg, Denver, CO,
Manning,
B.A. 2003. Arsenic and Selenium Speciation in
Environmental Remediation Materials.
Society of Western Analytical Professors. Cal. State University-Fullerton. February 28 and March 1. 2003.
Manning,
B.A., Hansel, C.M., Fendorf, S.E. 2002. Investigations of Arsenic and Iron
Interactions in Environmental Systems Using Synchrotron Radiation Techniques.
American Geophysical
Manning,
B.A., Dinh, K., Peterson, T.M., Gray, J. 2002. Oxyanion
Immobilization in Soil by Reactions with Zero-Valent
Iron Corrosion Products. Soil Science
Society Annual Meeting,
Manning,
B.A., Fendorf, S.E. and D.L. Suarez. 2001. Arsenic(III) Complexation
and Oxidation Reactions on Soil Mineral Surfaces. American Chemical Society
Annual Meeting,
Nguyen,
Q.T., Manning, B.A. 2001. Surface Complexation
Modeling of Lead Adsorption Reactions in Soil. American Chemical Society Annual
Meeting,
Manning,
B.A., Fendorf, S.E. and D.L. Suarez. 2000. EXAFS Analysis of As(III) and As(V) Reactions
With Fe and Mn Oxides. American Geophysical
Manning,
B.A., Suarez, D.L., and S.E. Fendorf. 1999.
Use of EXAFS-derived Oxyanion Surface
Structures in a Surface Complexation Model. Soil Science Society Annual Meeting,
Hunt, M.L.,
Manning, B.A., and C. Amrhein. 1999.
Sorption and Oxidation of Arsenic(III) on Zero‑Valent
Iron. Soil Science Society Annual
Meeting,
Bostick, B.C., Manning, B.A., and S.E. Fendorf. 1999. Arsenite Sorption on Metal Sulfides.Stanford
Synchrotron Radiation Laboratory (SSRL) Users Conference, Oct. 1999,
Manning,
B.A., Fendorf, S.E. and D.L. Suarez. 1999. Arsenate Surface Complexes in Soil and Model
Compounds. American Chemical Society
Annual Meeting,
Manning,
B.A. and D.L. Suarez. 1998. Use of Soil Physical and Chemical Properties
in a Kinetic Model for the Reactions of Arsenic(III) with Soil. American
Geophysical
Manning,
B.A. and D.L. Suarez. 1998. Modeling Arsenic(III) Adsorption and Heterogeneous
Oxidation Kinetics in Soils. Soil
Science Society of
Manning,
B.A., Fendorf, S.E., and S. Goldberg. 1997.
Arsenic(III) Coordination and Stability at the Goethite-Water Interface. Soil Science Society of
1997.
Manning,
B.A., and S. Goldberg. 1997. Adsorption
and stability of arsenic(III) at the clay mineral-water interface. American Chemical Society Annual Meeting,
Manning,
B.A., and S. Goldberg. 1996. Factors
affecting the arsenic(III) and arsenic(V) adsorption capacity oxide
minerals. Soil Science Society of
Manning,
B.A., and S. Goldberg. 1995. Arsenite adsorption on soil minerals at controlled redox potential. Soil Science Society of America Annual
Meeting, St. Louis, MO, October 29-November 3, 1995.
Goldberg,
S., and B.A. Manning. 1995. Application of surface complexation
modeling to competitive systems and natural samples. V.M. Goldschmidt Conf. Abst.
p. 49-50.
Manning,
B.A., and S. Goldberg. 1995. Surface complexation modeling of arsenate adsorption on soil minerals. American Chemical Society Annual Meeting,
Manning,
B.A., and S. Goldberg. 1994. Arsenate
competitive adsorption on soil minerals.
Soil Science Society of
Manning,
B.A., and R.G. Burau. 1993. Selenate
immobilization by in situ precipitation of iron oxyhydroxide. Soil Science Society of
Manning,
B.A., and R.G. Burau. 1992. Chemical immobilization
of selenium in evaporation pond sediments.
Society of Environmental Toxicology and Chemistry Annual Meeting,
Manning,
B.A., and R.G. Burau. 1992. Geochemical immobilization of selenium in evaporation
pond sediments. Soil Science Society of
Manning,
B.A., and R.G. Burau. 1991. Redox
transformations of selenium in evaporation pond sediments. Soil Science Society
of
Invited
Lectures
Nanometer-Scale
Metallic Iron Particles: Surface Chemistry and Reactions with Inorganic
Groundwater Contaminants.
Zerovalent Iron Surface Chemistry
and Reactions with Arsenic and Chromium.
Metallic Iron Surface Chemistry and Reactions with Arsenic
and Chromium.
Arsenic Speciation and Heterogeneous Redox
Reactions in Soil Systems. Soil Science
Society Annual Meeting, Denver, CO,
Investigations of Iron and Manganese Oxide Materials for
Remediation of Arsenic. Western Society
of Soil Science.
Environmental Surface Chemistry and Speciation of Toxic Trace
Elements. NIH Bridges student seminar.
Department of Chemistry,
Modern Analytical Techniques for Arsenic Speciation and
Surface Chemistry. Department of
Chemistry & Biochemistry,
Application of Ion Chromatography-Hydride Generation Atomic
Absorption Spectrometry to Arsenic Speciation in Soil. Soil Science Society of
Speciation and adsorption of arsenic on soil minerals. Department of Soil and Environmental Science,
Professional
Leadership and Service
Service at Professional Meetings
2003 Symposium
Co-organizer and Session Chair. Trace
Element Geochemistry in Soils: The Role
of Arsenic. Western Society of Soil
Science Meetings, San Francisco State Univ.,
2002 Session
Chair and Student Paper Judge. Soil
Science Society of
2001 Symposium
on Biogeochemistry of Environmentally Important Trace Elements. American Chemical Society Annual Meeting,
2000 Student
Presentation Evaluator. American
Geophysical
1999 Symposium
Organizer: Oxyanion Surface Chemistry and
Remediation in Soil and Geologic Media.
Soil Science Society of
Proposal
Reviewer
National
Science Foundation
USDA Small
Business Innovation Research (SBIR)
Stanford
Synchrotron Radiation Laboratory instrument time proposals
Textbook
Reviewer
Quantitative Chemical Analysis, 5th edition by Dan Harris. Freeman Publishers.
Manuscript
Reviewer
Environ.
Sci. & Technol.
Geochim. Cosmochimica Acta
J.
Environmental Quality
Chemosphere
Soil
Science
Soil
Science Society of
Applied
Geochemistry
J. Contam. Hydrol.
Geochem. Exploration
Water
Research